| 刘春玲,徐达,温俏,王洪旭,谢美思,朱东升.化学通报,2014,77(8):819-822. |
| 三环己基锡取代间苯二甲酸酯的合成、表征及热稳定性分析 |
| Synthesis, Characterization and Thermal Stability of a tricyclohexyltin Carboxylate Based on Substituted Isophthalic Acid |
| 投稿时间：2014-01-11 修订日期：2014-02-03 |
| DOI： |
| 中文关键词: 三环己基锡 晶体结构 热稳定性 |
| 英文关键词:tricyclohexyltin crystal structure thermal stability |
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| 中文摘要: |
| 以三环己基氢氧化锡为原料与取代的间苯二甲酸反应得到了含有萘二甲酰亚胺结构的有机锡羧酸酯。通过元素分析、红外光谱及核磁共振波谱等测试手段对该化合物进行了表征,并用X-射线单晶衍射仪测得其晶体结构。该化合物属于三斜晶系,空间群为P-1,晶胞参数：a =11.7829(7)? ,b =12.9965(8) ?,c =19.2944(12)?,α =92.6570(10)?, β =99.7970(10)?,γ =115.5100(10)?,V =2603.9(3)?3, Z = 2, Dc=1.397 mg/m3,R1 = 0.0362, wR2 = 0.0761。热重分析表明化合物具有良好的热稳定性。 |
| 英文摘要: |
| The reaction of tricyclohexyltin hydroxide with substituted isophthalic acid yielded the organotin carboxylate. The complex was characterized by elemental analysis, FT-IR, NMR (1H, 13C) spectroscopy and single-crystal X-ray diffraction. The structural analysis showed that the compound belongs to triclinic, space group p-1 with a =11.7829(7)? ,b =12.9965(8) ?,c =19.2944(12)?,α =92.6570(10)?, β =99.7970(10)?,γ =115.5100(10)?,V =2603.9(3)?3, Z = 2, Dc=1.397 mg/m3,R1 = 0.0362, wR2 = 0.0761. The thermal stability was also investigated. |
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