张日成,尹国辉,陈立功.化学通报,2014,77(6):526. |
可回收有机小分子催化不对称Michael加成的研究进展 |
Progress in Recyclable Organocatalysts Catalyzed Asymmetric Michael Additions |
投稿时间:2014-02-26 修订日期:2014-03-27 |
DOI: |
中文关键词: 可回收的 有机小分子催化剂 Michael加成 不对称催化 有机催化 |
英文关键词:Recylcable, Organocatalyst, Michael addition, Asymmetric catalysis,Organocatalysis |
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中文摘要: |
手性有机小分子催化不对称Michael加成反应是现在最热门的研究领域之一。手性有机小分子催化剂在拥有诸多优点的同时,也存在用量较大、回收利用难等的问题,因此手性有机小分子催化剂的回收利用这一课题成为了近几年的一个研究热点。本文根据催化剂的回收方法将近几年来可回收的手性有机小分子催化剂进行了分类,并介绍了它们在不对称Michael加成反应中的应用研究进展。 |
英文摘要: |
Organocatalysts catalyzed asymmetric michael addition has become one of the most intensively research fields. Organocatalysts have many advantages, meanwhile, there are some problems, such as high dosage and unrecyclable character. So, the recycling of organocatalysts has become a research hotspot. In this paper, the recyclable organocatalysts are classified by the recycling methods of them. The progress in the application of recyclable organocatalysts catalyzed asymmetric michael additions are also introduced. |
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