| 侯勇,朱屋彪,李志锐.化学通报,2014,77(12):1244-1247. |
| 正基于吡啶鎓阳离子对配合物的合成及表征 |
| Synthesis andCharacterization of a complex based on pyridinium cation |
| 投稿时间：2014-03-31 修订日期：2014-04-30 |
| DOI： |
| 中文关键词: 马来二氰基二硫烯镍(Ⅱ)配合物 结构 |
| 英文关键词:maleonitriledithiolate Nickel(II) complex, structure |
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| 中文摘要: |
| 合成了一种马来二氰基二硫烯镍(Ⅱ)配合物[2-NaMePyNH2]2[Ni(mnt)2]([2-NaMePyNH2] 为1-(2"-奈苄基)-2-氨基吡啶鎓离子),并用元素分析,UV,IR,单晶x-射线衍射表征了其组成和结构。结果表明：配合物系单斜晶系,空间群P21/c,a = 13.335(2)?,b = 7.9458(12)?,c = 17.480(3)?,α = 90o,β = 97.646(2)o,γ = 90o,V = 1835.7(5),Z = 2。 |
| 英文摘要: |
| A new complex, [2-NaMePyNH2]2[Ni(mnt)2] ([2-NaMePyNH2] is [1-(2"-naphthylmethyl)-2- aminopyridinium and mnt2- is maleonitriledithiolate) has been prepared and characterized by elemental analyses, UV, IR and single crystal X-ray diffraction. Complex crystallizes in the Monoclinic space group P21/c, a = 13.335(2)?, b = 7.9458(12)?, c = 17.480(3)?, α = 90o, β = 97.646(2)o, γ = 90o, V = 1835.7(5), Z = 2. |
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