| 罗杰伟,秦大斌,孙胜富,张仕禄,赵波.化学通报,2015,78(3):264-268. |
| 设计合成新型有机硒化合物用于金属阳离子识别性能研究 |
| The Design and Synthesis of a new organic selenium compounds to study the metal cation recognition performanceJie-wei Luo1,Da-bin Qin2,Shengfu-Sun2, Silu-Zhang1,Bo-Zhao1 |
| 投稿时间：2014-04-05 修订日期：2014-07-19 |
| DOI： |
| 中文关键词: 有机硒化合物 合成 汞离子识别 |
| 英文关键词:SorganicSselenium compounds Ssynthesis Smercuryion recognition |
| 基金项目:四川省教育厅项目(13ZB0096)和川北医学院科研发展计划项目(CBY12-A-ZP17)资助 |
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| 中文摘要: |
| 设计合成了1,4-二-(2-苄硒基)乙氧基蒽有机硒化合物,利用1HNMR、13CNMR、能谱和质谱对化合物进行了结构表征,采用荧光光谱技术研究了其对金属阳离子的识别.研究结果表明化合物(1,4-二-(2-苄硒基)乙氧基蒽对汞离子有较强的识别能力,且对汞离子表现出“on-off”开关性能,其应用和识别机理在进一步探讨之中。 |
| 英文摘要: |
| It was designed and synthesised about 1,4 - two - (2- Benzylseleno) ethoxy
Anthracene Compound, Which was characterized by Using 1H NMR、13C NMR spectrum and energy spectrum spectrometry,and studied about the recognition of metal ions by fluorescence spectr oscopy. The results show that1,4 - two - (2- Benzylseleno) ethoxy anthracene compound has strong recogn ition ability for mercury ion,and exhibit “on-off ”switch performance to the
mercury ions. Which was discussed about the recognition mechanismand application. |
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