| 刘磊,王梦岩,吕海军,王晓佳,张丽男,高子彬.化学通报,2015,78(3):215-219. |
| 三苯胺类小分子的合成及其AIE性能研究 |
| Triphenylamine and its Derivatives: Synthesis and Properties |
| 投稿时间：2014-09-23 修订日期：2014-09-30 |
| DOI： |
| 中文关键词: 聚集诱导发光 三苯胺 合成 |
| 英文关键词:Aggregation-induced-emission Triphenylamine Synthesis |
| 基金项目:国家自然科学基金项目(21102032)河北省高等学校科学技术研究项目(Z2013001)和河北科技大学平台开放课题项目(2014PT86)资助 |
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| 中文摘要: |
| 以二苯胺、碘苯、对碘甲苯以及对碘苯甲醚为原料,合成了三苯胺及其衍生物(4-甲氧基三苯胺、4-甲基三苯胺、4-醛基三苯胺、4-乙烯基三苯胺)T1~T5,并对其紫外-可见吸收光谱与荧光光谱进行了检测。结果表明,连有甲氧基、甲基、乙烯基取代基的三苯胺化合物在甲醇/氯仿的混合溶液中具有聚集诱导发光(AIE)性能；而醛基取代的4-醛基三苯胺表现出了聚集荧光淬灭(ACQ)现象。 |
| 英文摘要: |
| In this artical triphenylamine and its derivatives(with methoxy, methyl, aldehyde and vinyl group) T1~T5 were synthesized and characterized. The optical properties of these molecules were studied by UV-Vis spectra and fluorescence emission spectra. The results showed that triphenylamine and its derivatives with methoxy, methyl, vinyl group showed AIE features in methanol/chloroform mixtures with different methanol contents. However, the derivative with aldehyde group showed aggregation-caused quenching features. |
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