周学荣,张晓鹏.化学通报,2015,78(7):590-596.
SCR催化剂碱(土)金属中毒的研究进展
Research Progress on Alkali Poisoning of Selective Catalytic Reduction Catalysts
投稿时间:2014-11-12  修订日期:2015-01-04
DOI:
中文关键词:  选择性催化还原(SCR)  碱金属中毒  再生  密度泛函理论
英文关键词:Selective catalytic reduction(SCR), Alkali poisoning, Regeneration, Density Functional Theory(DFT)
基金项目:国家自然科学基金(51408098)、中央高校基本科研业务费专项资金(5001-852004)资助
作者单位E-mail
周学荣 大连理工大学 zxrzxr1989@126.com 
张晓鹏* 大连理工大学 xiaopengzhang@dlut.edu.cn 
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中文摘要:
      在SCR选择性催化还原烟气脱硝系统中,催化剂碱(土)金属中毒和再生受到广泛关注。本文综述了SCR脱硝催化剂碱(土)金属中毒的失活机理及基于分子水平上碱金属中毒的研究新思路,并根据催化剂的各种失活机理,有针对性地综述了提高催化剂抗碱金属中毒的途径及中毒催化剂的再生方法。
英文摘要:
      In the selective catalytic reduction (SCR) flue gas denitration system, alkali ,alkaline earth metal poisoning and regeneration of catalysts have aroused widespread concern. This paper describes and compares the research progress of alkali metal poisoning mechanism of the SCR denitration catalysts and research thought based on the molecular level. According to the mechanism of catalyst deactivation, the methods designed to improve the resistance to alkali metal and regeneration methods of poisoning catalyst are reviewed.
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