| 李亚妮,王为强,余秦伟,梅苏宁,王伟,张前,杨建明,吕剑.化学通报,2015,78(7):597-601. |
| 烯烃二胺化反应制备邻二胺化合物的研究进展 |
| The Development of Direct Vicinal Diamination of Alkenes |
| 投稿时间：2014-12-01 修订日期：2015-01-25 |
| DOI： |
| 中文关键词: 烯烃 邻二胺 分子内二胺化 分子间二胺化 催化剂 |
| 英文关键词:alkenes vicinal diamines intermolecular Diamination intramolecular Diamination catalysts |
| 基金项目: |
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| 中文摘要: |
| 介绍了通过烯烃二胺化反应路线制备邻二胺化合物的研究工作,对用于烯烃二胺化反应的类型及催化体系进行了综述,钯、铜金属催化剂及共价碘(Ⅲ)试剂对烯烃二胺化反应具有普遍适用性,环境友好的铜及非金属催化剂是未来研究的热点。 |
| 英文摘要: |
| The research work in direct diamination of alkenes to vicinal diamines was introduced. In this article, various reaction type and catalysts of diamination of alkenes are reviewed. Reagent combinations of palladium catalyst and copper catalyst or hypervalent iodine(III), respectively, represent the broad applicability. Copper catalyst and metal-free catalysts will attractive in future because of their environment friendly. |
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