| 龙冉,李睿,熊宇杰.化学通报,2015,78(7):580-589. |
| 以催化功能优化为导向的无机复合结构表界面和电子态调控 |
| Control over Surface/Interface and Charge State: Tuning Catalytic Performance of Inorganic Hybrid Structures |
| 投稿时间：2015-01-04 修订日期：2015-01-30 |
| DOI： |
| 中文关键词: 表界面 电子态 复合结构 催化 无机材料 |
| 英文关键词:Interface, Electronic state, Hybrid structure, Catalysis, Inorganic material |
| 基金项目:国家973计划（2014CB848900）、国家自然科学基金项目（21471141和21101145），中央高校基本科研业务费专项资金（WK2060190025，WK2310000035和WK2060190037），国家“青年千人计划”，中国科学院“百人计划”和中国博士后科学基金（2014M560514）资助 |
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| 中文摘要: |
| 本文概述了具有特定表界面的无机复合结构纳米晶体的可控合成方法,阐述了合成过程中的关键控制参数。以本课题组近年来的进展为例,重点讨论了复合结构的设计对纳米催化剂表界面状态和电子态的调控。纳米结构的表界面状态和电子态调控赋予了催化剂在反应分子吸附与活化中的独特行为,从而获得了不同于单一组分催化剂的优异催化性能。 |
| 英文摘要: |
| This review article summarizes the recent developments of inorganic hybrid nanostructures with specific surface/interface, with a focus on the key parameters in their controlled synthesis. Based on our recent process, we mainly discuss the design of hybrid structures for controlling their surface/interface and modulating their electronic states. The hybrid nanostructures possess unique properties in reaction molecular adsorption and activation enabled by the optimizations of surface/interface and charge state, which in turn exhibit superior performances in catalytic reactions to single-component catalysts. |
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