| 徐 珍,吕 早 生,孙昱.化学通报,2016,79(2):179-182. |
| 四丁基氟化铵在H2O-DMF中的电导研究 |
| Electrical Conductivity of Tetrabutylammonium Fluoride in water-N，N-Dimethyl Formamide Mixed Solvent |
| 投稿时间：2015-07-06 修订日期：2015-09-15 |
| DOI： |
| 中文关键词: 四丁基氟化铵 缔合常数 H2O-DMF混合溶液 摩尔极限电导 |
| 英文关键词:Tetrabutylammonium fluoride Association constants H2O-DMF mix solvent Limiting equivalent conductance |
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| 中文摘要: |
| 测量了298.15-328.15K温度范围内四丁基氟化铵在20(wt)%-80 (wt)% H2O/DMF混合溶液中的电导率，测得的电导率分别通过Kray-Bray方程和Shedlovsky方程分析，推导出了四丁基氟化铵在H2O-DMF混合溶液中的摩尔极限电导、缔合常数和离解常数，并计算出缔合反应的热力学参数（△Ga，△Ha，△Sa）；同时探讨了温度和混合溶剂的组成对摩尔极限电导、缔合常数和热力学参数的影响。 |
| 英文摘要: |
| Conductance measurements at temperatures range from 298.15 to 328.15k were performed for tetrabutylammonium fluoride(TBAF) in 20(wt)%-80 (wt)% water/DMF mixtures. The conductivity data had been analyzed using Kraus-Bray and Shedlovsky models, the limiting equivalent conductance, the association constants, dissociation constants and thermodynamic parameters of association（△Ga，△Ha，△Sa）for TBAF were calculated and discussed based on the effect of the temperature and the composition of solvent mixture on them. |
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