| 张纯喜,陈长辉,常文艳,董红星.化学通报,2016,79(1):4-9. |
| 自然和人工光合作用水裂解催化剂 |
| Catalysts for Water-Splitting Reaction in Natural and Artificial Photosynthesis |
| 投稿时间：2015-08-18 修订日期：2015-08-31 |
| DOI： |
| 中文关键词: 光合作用 光系统II 水裂解催化中心 人工模拟光合作用 Mn4Ca簇合物 |
| 英文关键词:Photosynthesis Photosystem II Catalytic center for water-splitting reaction Artificial photosynthesis Mn4Ca-cluster |
| 基金项目:国家自然科学基金（31070216, 91427303）资助 |
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| 中文摘要: |
| 近年生物光合作用水裂解催化中心的结构研究取得重要进展，这为人工模拟光合作用水裂解研究提供了理想的蓝图。人工模拟生物水裂解催化中心，制备高效、廉价人工水裂解催化剂，获得电能和(或)氢能，被认为是解决人类所面临的能源危机和环境污染问题的理想途径。这方面的研究具有重要科学意义和应用价值，同时也是广受关注的重大科学前沿。本文对最近生物水裂解催化中心和其人工模拟研究进展进行了评述。 |
| 英文摘要: |
| The structure of the catalytic center for water-splitting reaction in natural photosynthesis has been revealed recently, which provides a blueprint for the development of artificial water-splitting catalyst in artificial photosynthesis. Mimicking the natural catalyst to prepare efficient and low-cost artificial catalysts and produce electric energy and/or hydrogen energy by using sun light and water, has been considered to be an ideal way to solve the energy crisis and environmental pollution of our society. This field is a well-known major scientific frontier and may be crucial for both fundamental scientific research and potential application. Here, recent advance of the water-splitting catalyst in natural and artificial photosynthesis have been reviewed. |
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