| 邱晓敏,李 洋,宋江锋,周瑞莎.化学通报,2016,79(4):304-313. |
| 2,6-萘二甲酸构筑配合物的研究进展 |
| The Advance of 2,6-naphthalenedicarboxylic acid-Based Coordination Polymers |
| 投稿时间：2015-10-07 修订日期：2015-11-25 |
| DOI： |
| 中文关键词: 2,6-萘二甲酸 配位模式 配合物 应用性质 |
| 英文关键词:2,6-naphthalenedicarboxylic acid coordination modes coordination polymers application properties |
| 基金项目:国家自然科学青年基金项目(21201155)；山西省青年基金项目(2012021007-5，2013021008-6)；山西省优秀青年学术带头人支持项目；山西省“131”领军人才工程项目；中北大学理学院研究生创新基金项目。 |
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| 中文摘要: |
| 2,6-萘二甲酸是一个具有多个配位原子的线性刚性配体,迄今,已报道的2,6-萘二甲酸构筑的配合物有100多个,它们展现了丰富的拓扑结构和潜在的应用价值,但是有关2,6-萘二甲酸构筑配合物的综述至今未见报道。本文总结了2,6-萘二甲酸配体的结构特点以及配位模式,并按照金属离子的种类对2,6-萘二甲酸基配合物进行分类归纳总结。着重介绍了2,6-萘二甲酸配合物在气体吸附分离、光致发光、磁性及多相催化方面的应用性质,最后对该类配合物的发展前景进行了展望。通过这篇综述可以很好的了解2,6-萘二甲酸配合物的合成、性能及发展,对这类配体的研究有重要的意义。 |
| 英文摘要: |
| 2,6-naphthalenedicarboxylic acid is an linear and rigid ligand with multiple coordinating atoms. up to now, more than 100 2,6-naphthalenedicarboxylic acid-based coordination polymers have been reported. These coordination polymers show the abundant topological structures and potential application values, however, the relative review based on 2,6-naphthalenedicarboxylic acid-based coordination polymers were not reported. This paper mainly summarizes the structural characteristics and coordination modes of 2,6-naphthalenedicarboxylic acid ligand, and systematic reviews the research advance of 2,6-naphthalenedicarboxylic acid-based coordination complexes according to various species of metal ions in recent years. We focuses on the application properties of 2,6-naphthalenedicarboxylic acid-based coordination polymers in the gas adsorption and separation, photoluminescence, magnetism and heterogeneous catalysis aspects, Finally, the research prospects of these coordination polymers are prospected. The synthesis, properties and development status of the 2,6-naphthalenedicarboxylic acid-based coordination polymers can be well known through this review, and it is of great significance for the study of this type of ligands. |
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