| 王唯黎,王景芸,董晓哲,陈平.化学通报,2016,79(8):731-738. |
| 催化氧化降解木质素的研究进展 |
| Advances in catalytic-Oxidation degradation of lignin |
| 投稿时间：2016-01-05 修订日期：2016-02-24 |
| DOI： |
| 中文关键词: 木质素 催化 氧化降解 |
| 英文关键词:lignin, catalyze, oxidative degradation |
| 基金项目:中国石油化工股份有限公司科技项目（41405F） |
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| 中文摘要: |
| 综述了木质素催化氧化降解方面的研究，着重介绍了金属为催化中心的氧化降解（包括以O2和H2O2为氧化剂的催化氧化：金属有机催化氧化、金属/溴化物催化氧化、金属配合物催化氧化、金属复合氧化体系和钛矿型复合氧化物催化氧化、金属/分子筛催化氧化和以自身为氧化剂的催化氧化）、无金属催化氧化降解、微波辅助氧化降解、光催化氧化降解和电化学氧化降解。本文从所用催化剂、反应条件、反应机理等几个方面介绍了国内外学者在木质素氧化降解方面的研究进展。 |
| 英文摘要: |
| The studies on catalytic-oxidation degration of lignin in recent years are reviewed in this paper. Metal catalytic-oxidation(including the reaction carried out with O2 and H2O2 as the oxidants such as: organometal catalytic-oxidation, metal/bromide catalytic-oxidation, metal complexe catalytic-oxidation, multiple-metal oxidants and Perovskite-type Oxide catalytic-oxidation, metal/zeolites catalytic-oxidation and catalytic-oxidation by the oxidants themselves), metal-free catalytic-oxidation, microwave assisted oxidative, photocatalystic oxidization, electrochemical oxidation for upgrading lignin and lignin model compounds are introduced emphatically. In this paper, the progress of catalytic-oxidation degration of lignin is reviewed according to the different catalyzers, reaction condition and mechanism. |
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