| 齐慧,卢晓锋,张尚玺,邵向锋.化学通报,2016,79(9):787-792. |
| 硫原子桥联芳基取代/稠合四硫富瓦烯 |
| Arylthio-substituted/fused tetrathiafulvalenes |
| 投稿时间：2016-04-22 修订日期：2016-05-05 |
| DOI： |
| 中文关键词: 四硫富瓦烯 硫原子桥联 C-S偶联反应 动态分子碗 超分子组装。 |
| 英文关键词:Tetrathiafulvalene, sulfur-bridge, C-S coupling, dynamic molecular bowl, supramolecular assembly. |
| 基金项目:国家自然科学基金委优秀青年基金 |
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| 中文摘要: |
| 近年来,四硫富瓦烯(Tetrathiafulvalene, TTF)衍生物的设计合成、超分子组装、组装材料的物理性能研究及其在有机电子器件中的应用引起了广泛的研究兴趣。在本论文中,我们简略综述关于“硫原子桥联芳基取代/稠合四硫富瓦烯衍生物 (Ar-S-TTF)”的最新研究进展,包括其高效合成、电化学及光学性能研究、分子的结构特征/空间堆积方式,以及此类分子与球形原子簇(富勒烯、杂多酸)之间的超分子组装及组装材料的性能。 |
| 英文摘要: |
| Tetrathiafulvalene (TTF) and its derivatives have received tremendous attentions owing to their applications in organic electronics. The research of TTFs includes the design and synthesis of functional molecules, supramolecular assembly, and elucidation of the physical properties of the supramolecular materials. Herein, we report the recent progress on arylthio-substituted/fused TTFs (Ar-S-TTF), on which the aryls are decorated onto the TTF core through the connection of sulfur bridges. We mainly highlight the facile synthesis, optical/electrochemical property, and structural feature of Ar-S-TTF, as well as the supramolecular assembly of Ar-S-TTF with fullerene and Keggin-type phosphomolybdic acid. |
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