| 李启彭,罗家刚,和晓全,张泽俊.化学通报,2016,79(11):1021-1027. |
| 手性配位聚合物的构筑及其应用 |
| Construction and Application of Chiral Coordination Polymers |
| 投稿时间：2016-06-10 修订日期：2016-07-18 |
| DOI： |
| 中文关键词: 手性配合物 构筑 分离 催化 多铁 |
| 英文关键词:chiral coordination polymers construction separation catalysis ferroelectric |
| 基金项目:云南省应用基础研究计划项目（2016FD083）和云南省教育厅科学研究基金资助性项目（2016ZZX229） |
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| 中文摘要: |
| 手性配合物因其结构多样性、可调控性以及潜在的多功能性,已经成为当前化学和材料学的研究热点。在手性配合物的合成中,可以通过选择特定的非手性配体、手性配体、手性溶剂或手性模板剂等来构筑手性配合物。此外,还可以选择特定的金属离子赋予目标手性配合物光、电、磁、催化和非线性等性能。本文详细地综述了近年来纯手性配合物的合成方法,以及在手性分离、手性催化、非线性、铁电和多铁等领域的应用研究进展。最后,对手性配合物的合成方法及应用前景进行了展望。 |
| 英文摘要: |
| Chiral coordination polymers (CPs) have become present research focus in chemistry and materials science due to their structural diversities and adjustability, and potential multifunctional properties. In the synthesis of chiral coordination polymers, we generally choose achiral ligands, chiral ligands, chiral solvents and chiral templates in order to obtain chiral coordination polymers. In addition, by selecting the specific metallic cations, we embed the as-prepared chiral coordination polymers with the fluorescent, electric, magnetic, catalytic and nonlinear properties. In this work, the research progresses on synthesis methods and applications of chiral coordination polymers in which chiral separation, chiral catalysis, nonlinear optics, ferroelectric and multiferroic properties are discussed in detailed. Finally, the synthesis methods and applications of chiral coordination polymers are prospected. |
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