| 郭芳杰,郭亚楠,夏立娜,孙京.化学通报,2017,80(4):329-333. |
| 咪唑类氮杂环卡宾金属配合物的合成与应用研究进展 |
| Recent Advances in Synthesis and Application of Imidazole N-Heterocyclic Carbene Metal Complexes |
| 投稿时间：2016-07-27 修订日期：2016-09-01 |
| DOI： |
| 中文关键词: N-杂环卡宾 螯合型化合物 合成 应用 |
| 英文关键词:N- heterocyclic carbene Chelate-type compounds Synthesis Application |
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| 中文摘要: |
| 氮杂环卡宾 (NHC) 具有独特的结构和性质,可合成大量的氮杂环卡宾金属化合物,现在已发展为催化领域的重要配体之一,一直受到大量研究者的关注。本文综述了以咪唑作为基本单元搭载不同的杂原子基团,合成一系列具有单齿、双齿和多齿型金属螯合物的方法及其在 Suzuki 偶联、Heck 偶联等反应中的应用。 |
| 英文摘要: |
| N-Heterocyclic carbene can be used to synthesize a variety of heterocyclic carbene metal compounds due to its unique structure and properties. Now NHC has been developed as one of the important ligands in the field of catalysis and has been the focus of a large number of researchers. The synthesis methods of metal complexes with monodentate, bidentate and multidentate using imidazole as the basic unit equipped with different heteroatomic groups were reviewed in this paper, and the application in the Suzuki coupling reaction, Heck coupling reactions reactions were also summarized. |
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