| 李海莹,刘峥,郭亚晋,郭 鹏,劳星乔,张淑芬.化学通报,2017,80(8):765-771. |
| 对甲酰基苯甲酸金刚烷酯席夫碱及其镍(Ⅱ)配合物的合成、表征及性质研究 |
| Syntheses, Characterizations and Properties of 4-Formyl-benzoic acid adamantan-1-yl ester Schiff Base and Their Ni(Ⅱ) Complexes |
| 投稿时间：2016-10-21 修订日期：2017-01-03 |
| DOI： |
| 中文关键词: 金刚烷醇 席夫碱 镍配合物 荧光性质 电化学活性 |
| 英文关键词:Adamantanol, Schiffbase, Ni(Ⅱ) complexes, Fiuorescenceproperty, Electrochemical activity |
| 基金项目:国家自然科学基金(21266006)；广西自然科学基金(2016GXNSFAA380109) 资助项目 |
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| 中文摘要: |
| 以金刚烷醇、4-甲酰苯甲酸和邻氨基苯酚、邻氨基苯硫酚、邻溴苯胺为原料合成了三种不同的对甲酰基苯甲酸金刚烷酯席夫碱及其镍(Ⅱ)配合物(H1、H2、H3),利用红外光谱、紫外-可见光谱、核磁共振氢谱对其进行结构表征,同时通过荧光光谱、热重分析和电化学分析对席夫碱及其镍(Ⅱ)配合物的荧光性质、热稳定性、电化学性质进行研究,结果表明,镍(Ⅱ)配合物H1、H2和H3均具有良好的荧光性质,且H1、H2具有较高的电化学活性。 |
| 英文摘要: |
| Three different Schiff bases containing adamantanyeof ester formyl benzoic acid and their Ni(Ⅱ) complexes(H1,H2,H3) were synthesized using adamantanol, 4-formylbenzoic acid, o-aminophenal, 2-aminothiophenol and 2-bromoaniline as raw materials. Their structures were characterized by IR, UV-Vis and NMR spectroscopies. The fluorescence properties,thermal stabilities and electrochemical properties of Schiff bases and their Ni(Ⅱ) complexes were studied through fluorescence spectra, thermogravimetric analysis and electrochemical techniques. The results indicated that Ni(Ⅱ) Complexes H1,H2 and H3 have good fluorescence properties and H1、H2 exhibit electrochemical activity. |
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