黄珍霞,梁峰,张海军,刘思敏.化学通报,2017,80(7):621-630.
含Co或Ni的双金属及三金属纳米颗粒制备方法及其催化制氢性能
Preparation Methods of Co and Ni Containing Bi- or Tri-metallic Nanoparticles and Their Catalytic Performance for Hydrogen Generation
投稿时间:2016-12-22  修订日期:2017-03-08
DOI:
中文关键词:  Co Ni 双金属纳米颗粒  三金属纳米颗粒 制备方法  催化制氢性能
英文关键词:Cobalt, Nickel, Bimetallic  nanoparticles, Trimetallic  nanoparticles, Preparation  methods, Catalytic  performance for  hydrogen generation
基金项目:国家自然科学基金面上项目(51472184, 51472185);湖北省教育厅高等学校优秀中青年科技创新团队计划(T201602)
作者单位E-mail
黄珍霞 武汉科技大学 1392693710@qq.com 
梁峰 武汉科技大学  
张海军* 武汉科技大学 zhanghaijun@wust.edu.cn 
刘思敏 武汉科技大学  
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中文摘要:
      常见的氢气储存方法有液态储氢、高压气态储氢、有机化合物储氢、金属氢化物储氢、吸附储氢及液相化学储氢材料储氢等,其中液相化学储氢材料由于具有含氢量高、且可按时即需释放氢气的优点,引起了研究人员的广泛关注;选择合适的催化剂催化液相储氢材料制氢已成为一个研究热点。含有Co或Ni的双金属或三金属纳米颗粒是一种极具应用前景的催化剂,具有价格低廉、储量丰富和催化性能优异等众多优点。本文综述了含Co或Ni的双金属或三金属纳米颗粒的制备方法及其催化制氢性能,并提出了其目前研究中存在的问题和未来潜在的发展方向。
英文摘要:
      Liquid hydrogen storage, high pressure gaseous hydrogen storage, organic compounds hydrogen storage, metal hydride hydrogen storage, adsorption hydrogen storage and liquid phase chemical hydrogen storage materials are widely used for storage of hydrogen. Among these methods, the liquid phase chemical hydrogen storage materials attracted considerable attention due to their high hydrogen content and easy control of the hydrogen generation rate and hydrogen purity. The study on preparation of appropriate catalysts for hydrogen production from liquid hydrogen storage materials has become a hot research topic. Owing to their low cost, abundance in earth, and good catalytic performance, Co or Ni containing bi- or tri-metallic nanoparticles (NPs) have become promising catalysts for hydrogen generation. In this review, the preparation methods of Co and Ni containing bi- or tri-metallic NPs and their catalytic performance for hydrogen production are summarized in detail, the disadvantages and potential development directions of Co and Ni based bi- or tri-metallic NPs are also proposed.
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