| 张睿,顾晓龙,庞欢.化学通报,2017,80(10):958-962. |
| 两种含有四硫富瓦烯羧酸基和1,10-菲啰啉配体的金属配合物的合成、结构及光学性质研究 |
| Synthesis, Structures and Spectral Properties of Two New Coordination Complexes Constructed with Tetrathiafulvalene Carboxylate and 1,10-Phenanthroline |
| 投稿时间：2017-03-16 修订日期：2017-04-20 |
| DOI： |
| 中文关键词: TTF羧酸盐配合物, 晶体结构, 紫外光谱, 荧光, 电化学性质 |
| 英文关键词:coordination complexes constructed by TTF-dicarboxylate salt, crystal structures, UV–Vis spectrum, fluorescence spectrum, electrochemistry Properties |
| 基金项目:国家自然科学基金项目(21671170) |
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| 中文摘要: |
| 本文用一种水溶性的TTF羧酸盐PropylTTFK2 (1)合成了两种金属配合物，Zn(L1)(Phen)2 (化合物3)
和Cd(L1)(Phen)2?(化合物4) (L1=PropylTTF2-; Phen=1,10-phenanthroline)。用元素分析对二者进行了测试，并解析了二者的晶体结构，具有明显的分子间S???S及H键作用。同时也测定了二者的紫外、荧光和电化学性质，滴定显示两种化合物均是很好的TCNQ电子接受体。 |
| 英文摘要: |
| In this paper, two mononuclear coordination complexes Zn(L1)(Phen)2?CH3OH?2H2O (3) and Cd(L1)(Phen)2?2CH3OH?H2O (4), (L1=PropylTTF2-; Phen=1,10-phenanthroline) derived from 1 (A water-soluble TTF-dicarboxylate salt PropylTTFK2 (1) (PropylTTFK2= Propy-lenedi--thio-4'',5''-tetrathiafulavale-
-ne-4,5-dicarboxylate dipotassium salt)), have been prepared. The structures have been characterized by EA. The crystal structures of 3 and 4 have also been determined by X-ray crystallography. Noticeable inter molecular S???S or/and H-bonding interactions have been found in 3 and 4, resulting in the formation of 1D chain. All of them have been fully characterized by UV–Vis, fluorescence spectrum and electrochemistry. The titration of TCNQ shows these compounds can form classical electron-acceptor salt with TCNQ. |
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