钟克利,王禹童,于奇轩,汤轶伟,侯淑华,边延江,汤立军.化学通报,2018,81(1):37-44. |
基于4-(N, N-二乙氨基)水杨醛席夫碱类荧光探针的研究进展 |
Progress in Fluorescence Probes Based on 4-(N, N-Diethylamino)salicylaldehyde Schiff Base |
投稿时间:2017-08-03 修订日期:2017-09-01 |
DOI: |
中文关键词: 4-( N, N-二乙氨基)水杨醛 席夫碱 荧光探针 识别 |
英文关键词:4- (N, N-Diethylamino)salicylaldehyde, Schiff base, Fluorescent probe, Recognition |
基金项目:辽宁省科技厅自然科学基金项目(20170540019)资助;国家自然科学基金项目(21304009, 21476029)资助 |
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中文摘要: |
4-( N, N-二乙氨基)水杨醛是染料及有机合成的重要中间体,也是具有亲水性质的生色团,其醛基常被用来制备席夫碱进而开发新颖的探针分子。本文介绍了对于一些常见离子如Al3+、Cu2+、Zn2+、Hg2+、Co2+、F-、CN-等进行荧光识别和检测的基于4-(N, N-二乙氨基)水杨醛合成的席夫碱类荧光探针,这些探针具有较高的选择性和灵敏度,并有很好的细胞通透性和较低的细胞毒性,有一定的实用价值。本文为此类荧光探针在环境、生物、食品中的实际检测和应用研究提供了理论依据和实践基础。 |
英文摘要: |
4- (N, N-Diethylamino)salicylaldehyde is an important intermediate in dye and organic synthesis, as well as a well-known chromophore with a hydrophilic character. Its aldehyde groups are often used to prepare Schiff bases and to develop novel probe molecules. In this paper, several kinds of Schiff base fluorescent probes based on 4-(N, N-Diethylamino)salicylaldehyde that applied in the detection of some common ions such as Al3+、Cu2+、Zn2+、Hg2+、Co2+、F-、CN- were introduced. Most of the probes can accurately and rapidly recognize ions with high selectivity and sensitivity. Some fluorescent probes have good cell permeability and low cytotoxicity and have a certain practical value. These studies provide a theoretical and practical basis for such fluorescent probes to be used in environment, biology and food detection applications. |
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