王稼国,荆西平.化学通报,2018,81(3):278-287. |
金属卤化物的水溶性 |
Solubilities of Metal Halides in Water |
投稿时间:2017-10-08 修订日期:2017-11-26 |
DOI: |
中文关键词: 金属卤化物,水溶性,结构,化学键 |
英文关键词:Metal halide, solubility in water, chemical bond, structure |
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中文摘要: |
金属卤化物水溶性规律一直是困扰大一新生的问题。本文从原子结构和分子结构出发归纳了金属卤化物的化学键,再根据化学键的强弱分析其水溶方式,同时配以热力学数据讨论了其溶解过程中的能量变化,最后归纳出了金属卤化物的水溶性规律。 |
英文摘要: |
The first-year undergraduates are always racked by the solubility rule of metal halides in water. In the paper, firstly, the chemical bonds were deduced from atomic structures and molecular structures;then, the dissolve modes in water were derived from the chemical bonds;thirdly,the correlation between the energy changes and the solubilities were analyzed based on thermodynamic data; and finally, the solubility rule of halides in water were revealed. |
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