| 胡为阅,宋修艳,卞兆荃,刘福胜.化学通报,2018,81(4):319-325. |
| 深共熔溶剂在有机反应中的应用 |
| Application of Deep Eutectic Solvents in Organic Reactions |
| 投稿时间：2017-10-23 修订日期：2017-12-17 |
| DOI： |
| 中文关键词: 深共熔溶剂 催化剂 有机反应 |
| 英文关键词:Deep eutectic solvents, Catalyst, Organic reaction |
| 基金项目:国家自然科学基金项目(51673106)和山东省科技攻关专项(2016GSF116005)资助 |
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| 中文摘要: |
| 深共熔溶剂（DES）作为一种低共熔混合物，由于具有廉价易得、蒸汽压低、无毒性、不易燃、可生物降解、可调控以及易循环使用等优点，逐渐成为一种新型的绿色溶剂或催化剂。本文介绍了DES的组成、分类，重点综述了DES作为溶剂或催化剂应用于常见的加成、取代、偶联、缩合、环化、酯化、多组分及解聚等有机反应。最后展望了DES在有机反应中的发展前景。 |
| 英文摘要: |
| As a low-temperature eutectic mixture, deep eutectic solvent (DES) with some remarkable properties such as low cost, negligible vapor pressure, non-toxicity, non-flammablility, biodegradablity, adjustablility and recyclability, which makes DES gradually become a new type of green solvent or catalyst. In this paper, the composition and classification of DES were introduced, and the applications of DES as a solvent or catalyst in some organic reactions, including addition, substitution, coupling, condensation, cyclization, esterification, multi-component and depolymerization reactions, were reviewed. Finally, the prospect of DES in organic reactions is forecasted. |
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