| 翟国庆,于宗江,江涛,孙伟之.化学通报,2018,81(7):579-585,597. |
| C—N键断裂的研究进展 |
| Research Progress on Cleavage of C—N Bond |
| 投稿时间：2018-01-09 修订日期：2018-02-06 |
| DOI： |
| 中文关键词: C—N键断裂 过渡金属催化 光催化 生物酶催化 |
| 英文关键词:C—N bond cleavage, Transition-metal-catalyzed, Photocatalysis, Enzyme catalysis |
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| 中文摘要: |
| C—N键作为常见的化学键广泛分布在有机分子中,C—N键的活化断裂在有机反应与生命化学过程中扮演重要的角色。文章从过渡金属催化、强氧化剂氧化、光催化、生物酶催化与其他方法五个方面概述了断裂C—N键的方法,对其优缺点、机理进行总结分析,并指出目前面临的挑战及发展方向。 |
| 英文摘要: |
| The C—N bond as a common chemical bond widely exists in many organic molecules and biomacromolecules. The formation and cleavage of C—N bonds play a crucial role in the process of organic reactions and biochemistry. This review summarizes the cleavage of C—N bonds from transition-metal-catalyzed, strong oxidization, enzyme catalysis, photocatalysis and other methods. Their advantages and disadvantages, reaction mechanism, challenges, development directions were also discussed． |
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