| 张怀远,唐蓉萍,伍家卫,胡雨来.化学通报,2018,81(8):681-691. |
| 三价碘试剂促进的氧化反应研究进展 |
| Progress in the Oxidation Reactions Promoted by Trivalent Iodine Reagents |
| 投稿时间：2018-02-14 修订日期：2018-04-09 |
| DOI： |
| 中文关键词: 三价碘试剂 氧化反应 氧化官能团化 |
| 英文关键词:Trivalent iodine reagents, Oxidation reaction, Oxidation functionalization |
| 基金项目:甘肃省高等学校科研项目（2017C-25）;甘肃省高等学校科研项目（2017D-26） |
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| 中文摘要: |
| 三价碘试剂的反应性能类似于过渡金属如汞、钛和铅,并且具有环境友好、价值低廉、反应条件温和、反应后处理简单和商业可利用的特点,因此,在有机合成中得到广泛的应用,特别是作为一种高效的选择性氧化试剂,受到广大有机化学家的亲睐。本文就三价碘试剂促进的氧化反应,从醇的氧化、羰基化合物的氧化官能团化到氧化硒化和铋化等14类反应进行了简单的综述。 |
| 英文摘要: |
| Trivalent iodine reagents of possess reactivity similar to that of transition metals such as Hg, Ti and Pb, but have the advantage of environment-friendly, low cost, mild reaction conditions, easy handling and commericial availaiblity. These compounds are widely used in organic synthesis, especially, as efficient selective oxidants which were given the attention by organic chemists. In this review, 14 kinds of oxidation reactions mediated by trivalent iodine reagents are briefly summarized, including alcohol oxidation, oxidative functionalization of carbonyl compounds, to selenylation reactions and bismuthlation reactions. |
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