| 刘双,刘澜涛.化学通报,2019,82(2):108-113. |
| 胺功能化配体PCPs材料碳捕捉和封存的研究进展 |
| Recent Advances in Carbon Capture and Sequestration of PCPs Synthesized by Amine-Functionalization Ligands |
| 投稿时间：2018-08-15 修订日期：2018-09-30 |
| DOI： |
| 中文关键词: 配位聚合物 胺功能化 二氧化碳 多孔材料 |
| 英文关键词:coordination polymer, amine-functionalization, carbon dioxide, porous materials |
| 基金项目:国家自然科学基金项目（21503129、21572126、21675109）, 河南省高等学校重点科研项目（15A150073） |
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| 中文摘要: |
| 近十年,多孔配位聚合物(porous coordination polymers, PCPs)因其晶体结构中可调节的孔道尺寸、形状以及化学功能化,在小分子的选择性吸附及分离领域受到了极大的关注。基于环境问题的严峻性,胺功能化PCPs材料对煤电厂燃烧废气中CO2优异的选择性吸附性能,使其在该领域拥有较好的应用潜力。本文综述了含末端氨基配体的PCPs材料应用于二氧化碳捕捉及存储的代表性工作,并对所存在的问题及发展方向进行了分析总结。 |
| 英文摘要: |
| Over the decade, porous coordination polymers (PCPs) have attracted significant attention in the area of selective adsorption & separation of small molecules due to their unique crystal structure with the tunable pore size, pore shape and chemical functionalization. Based on the severity of environmental problems, amines modified PCPs have exhibited outstanding selective adsorption property for carbon dioxide from flue gas, which offer great potential application in this field. In this review, the problems and development of PCPs synthesized by bridging ligands contain terminal amines groups are discussed alongside marked examples applied for carbon dioxide capture and sequestration. |
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