| 胡子乔,刘贵传,孔勇,林永学,金军斌.化学通报,2019,82(1):32-36. |
| 环钯化合物合成及其在催化中的应用 |
| Synthesis and Catalytic Application of Palladacycles Complexes |
| 投稿时间：2018-09-07 修订日期：2018-09-28 |
| DOI： |
| 中文关键词: 环钯化合物 合成 催化 |
| 英文关键词:Palladacycles, Synthesis, Catalysis |
| 基金项目:国家科技攻关计划 |
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| 中文摘要: |
| 环钯化合物由于丰富的结构、高度的稳定性和卓越的催化性能，已成为钯化学研究的热点之一。人们已开发出了C-H键活化、氧化加成、转金属化、亲核加成和配体交换等多种方法，可制备出从三元环到十一元环的CY 型环钯化合物和多种YCY型环钯化合物。环钯化合物目前已应用于烯烃氢化、偶联反应和不对称催化等反应中。本文简单介绍了环钯化合物的种类，重点介绍了环钯化合物的合成方法和催化应用情况。最后提出了环钯化合物在今后合成研究和催化应用中的发展建议。 |
| 英文摘要: |
| Palladacycles complexes have become a hot motif in the research of Palladium chemistry, because of abundant structures, high stability and excellent catalytic properties. A number of synthesis methods have been developed, such as C-H bond activation, oxidation addition, metal transfer, nucleophilic addition, and ligand exchange. The CY type Palladacycles complexes from ternary ring to eleven-membered ring and YCY type Palladacycles complexes have been afforded. Palladacycles complexes have been utilized in olefin hydrogenation, coupling reaction, asymmetric catalysis, and other reactions. The types of Palladacycles complexes were briefly introduced, in this article. The synthesis methods and application for catalytic reactions of Palladacycles complexes were focused on. The development suggestions of Palladacycles complexes for synthesis and catalytic application were proposed. |
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