| 钱文浩,李富盛,黄玮,丛玉凤.化学通报,2019,82(2):99-107. |
| MOFs材料在传感器的应用 |
| The applications of MOFs in sensors |
| 投稿时间：2018-09-10 修订日期：2018-10-11 |
| DOI： |
| 中文关键词: 金属有机骨架材料 配位聚合物 传感器 识别 选择性 灵敏性 |
| 英文关键词:MOFs PCPs sensors recognize selectivity sensitivity |
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| 中文摘要: |
| 摘 要 金属有机骨架（Metal Organic Framework，MOFs）是由有机配体与金属离子或金属离子簇通过配位作用自组装而成的一种具有永久孔道性的开放结晶骨架，通常也被称为配位聚合物（PCPS）。因为其较大的比表面积、规整的孔道结构、热稳定性和化学可裁剪性，使其在多个领域具有广阔的应用前景。近年来，随着MOFs在传感领域的发展，许多不同的功能基团被引入到MOFs的孔道中，研制出具有荧光识别性能的MOFs。本论文综述了近几年来基于MOFs的化学传感器在离子识别、PH检测、挥发性有机物和气体检测、爆炸物识别和生物分子检测等关键领域的研究进展，并对MOFs在化学传感器的应用前景进行了展望。 |
| 英文摘要: |
| Abstract Metal–organic frameworks (MOFs), also called porous coordination polymers（PCPs）,are a class of crystalline porous materials built from organic linkers and metal ions/clusters. The unique features of MOFs, including high surface area, uniform channels, thermal stability and tailorability enable them have great potential applications in many fields. As the subfield of MOF-based sensing has developed，MOFs with fluorometric sensing properties have been developed by introducing many diverse chemical functionalties. This comprehensive review summarizes the topical developments in a number of crucial sensing domains, including ionic species, pH, volatile organic compounds and gas, explosives, biomolecules, and many others, also prospect the development trend of MOFs in chemical sensors. |
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