| 孙娜,王海彦,吴海琳,杨占旭,王钰佳.化学通报,2019,82(4):329-333. |
| 导向剂法制备SAPO-11分子筛及其加氢异构化性能 |
| Preparation and Hydroisomerization Properties of SAPO-11 Molecular Sieve by Targeting Agent Method |
| 投稿时间：2018-10-25 修订日期：2018-11-26 |
| DOI： |
| 中文关键词: 导向剂法 小晶粒 介孔 SAPO-11分子筛 |
| 英文关键词:guiding agent method small grain mesoporous SAPO-11 molecular sieve |
| 基金项目:国家自然科学基金项目（2016-Z0030） |
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| 摘要点击次数: 2004 |
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| 中文摘要: |
| 采用导向剂法在模板剂用量减半的条件下成功合成小晶粒介孔SAPO-11分子筛。对合成分子筛的形貌、孔结构和酸类型进行表征；以长链烷烃正十二烷作为反应原料，考察Pt负载量为0.5 %(质量分数)的 SAPO-11分子筛的加氢异构化反应性能。结果表明:将模板剂使用量减半合成的SAPO-11分子筛，晶粒尺寸约为3 μm，介孔比表面积为113.3 m2/g以及介孔孔容为0.328 m3/g ，异构烃收率达到65.31 %。 |
| 英文摘要: |
| The mesoporous SAPO-11 molecular sieve with small grains was successfully synthesized by the guidance agent method under the condition of reducing the amount of template agent. The crystal structure , elemental composition,surface area, pore volume, and acidity of the catalyst was thoroughly characterized. The catalytic hydroisomerization performance of SAPO-11catalysts with 0.5 % Pt loading was evaluated with n-dodecane as a material. The results show that the SAPO-11 molecular sieve synthesized by halving the amount of template has a grain size of about 3 μm,the mesoporous surface area is 113.3 m2/g and the mesoporous volume is 0.328 m3/g, the isomer yield was 65.31%. |
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