| 陈功东.化学通报,2019,82(6):566-575,515. |
| 鲍林的化学键的思想起源 |
| Intellectual Origins of the Chemical Bond Theory of Linus Pauling |
| 投稿时间：2019-03-05 修订日期：2019-04-01 |
| DOI： |
| 中文关键词: 化学键 鲍林 晶体结构 量子力学 理论和实验 |
| 英文关键词:Chemical bond, Linus Pauling, crystal structure, quantum mechanics, theoretical and empirical |
| 基金项目:国家留学基金委建设高水平大学公派留学 |
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| 摘要点击次数: 1975 |
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| 中文摘要: |
| 化学键是化学与物理学在二十世纪早期产生交融的重要问题，其中以美国化学家鲍林在三十年代提出的价键理论最有影响力。该理论同时具有化学和物理学的多个思想来源，时间上从十九世纪后期的经典结构化学一直分布到当时刚诞生的量子力学，以及路易斯化学键理论、X射线晶体学和物理化学。物理学比化学的影响更广，但两种来源都注重实验，演化历程中理论向实验靠拢的程度更大。 |
| 英文摘要: |
| Chemistry and physics interacted considerably on the problem of chemical bond during the early twentieth century, and among them stood out Linus Pauling’s valence bond theory in the 1930s as from a chemist. Pauling’s work had several origins from both chemistry and physics, ranging chronologically from classical structural chemistry in late nineteenth century to quantum mechanics just coined then, and those training him directly including the chemical bond theory of Lewis, X-ray crystallography, and physical chemistry. Physical origins have more prominent influence than chemical, while both sorts regard experiment, and theoretical aspects show more convergence to the empirical than the reverse. |
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