| 袁阳蕾,陈欣,王红梅,陈清.化学通报,2019,82(8):696-705. |
| 配位型钯离子荧光探针的研究进展 |
| Progress of Coordination-based Fluorescent Probes for Palladium Ion |
| 投稿时间：2019-03-20 修订日期：2019-04-22 |
| DOI： |
| 中文关键词: 钯离子，荧光探针，配位 |
| 英文关键词:Palladium, Fluorescent Probe, Coordination |
| 基金项目: |
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| 中文摘要: |
| 钯离子在珠宝行业、工业催化、制药行业中应用广泛,也是汽车尾气排放装置触媒转换器中的最重要的催化剂之一,但残留的钯离子对人体健康和环境有着极大的危害。近几年,人们对于钯离子残留的检测越来越重视,而配位型金属离子荧光探针是最方便且能快速检测离子的一种方法。本文根据配位方式的不同,综述了近十几年来配位型钯离子荧光探针的研究进展,包括氮族元素配位(如N和P)的荧光探针,氧族元素配位(如O,S和Se)的荧光探针,杂原子配位(同时含有氮族元素和氧族元素为配位原子)的荧光探针,不饱和键配位的荧光探针以及聚合物荧光探针等。对不同配位方式、探针结构及对钯的检测效果进行了分析,希望能够为设计更灵敏、更高效的配位型钯离子荧光探针提供启发。 |
| 英文摘要: |
| Palladium ion is widely used in industrial and medicial areas, but the residual Pd2+ has a great harm to human health and environment. In recent years, more and more attention have been paid to sensitively detect the residual Pd2+. Among them, coordination-based fluorescent probes are designed, which have been developed to be one of the most convenient and rapid assays for the detection of Pd2+. In this paper, according to the coordination modes, coordination-based fluorescent probes are reviewed, including the coordination through N group elements (such as N、P), O group elements (such as O, S, Se) , N group elements and O group elements, unsaturated bond and even polymers. Through analyzing coordination modes, fluorescent probe structure, and detection efficiency, the review could provide a clue to further design more sensitive and efficient fluorescent probes for Pd2+ detection. |
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