| 唐梓桓,张财顺,张磊,刘道胜.化学通报,2019,82(9):796-800. |
| 含氟硼二吡咯单元金属有机骨架材料的研究进展 |
| Progress in MOFs Materials Containing BODIPY Unit |
| 投稿时间：2019-04-13 修订日期：2019-05-21 |
| DOI： |
| 中文关键词: MOFs 光物理过程 Bodipy 光吸收天线 自组装 |
| 英文关键词:MOFs, Photophysical process, Bodipy, Light absorbing antenna, Self assembly |
| 基金项目:辽宁省教育厅科学研究经费项目，L2019012、辽宁石油化工大学博士启动基金项目、中国石化有限公司催化剂分公司横向课题（2015040237）（2018040192） |
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| 中文摘要: |
| MOFs是一种具有高度有序孔道结构和较大比表面积的材料，而含氟硼二吡咯（BODIPY）发色团的MOFs材料是将BODIPY发色团设计成可与金属中心配位的配体并直接与金属离子配位或将该发色团作为光吸收天线引入到MOFs材料中所制备的材料，此类材料因对可见光有较强的吸收而受到广泛关注。本文总结了含BODIPY发色团MOFs材料的制备方法，探讨了此类材料的结构特点、光物理性质及应用前景，最后展望了未来此类材料的前景和发展趋势。本文可为BODIPY发色团的MOFs材料在光化学领域的发展提供参考。 |
| 英文摘要: |
| MOFs is a kind of material with highly ordered pore structure and large specific surface area, MOFs containing BODIPY chromophore are materials prepared by designing BODIPY chromophore as a ligand that can coordinate with metal centers and directly coordinate with metal ions, or introducing the chromophore into MOFs materials as an optical absorption antenna. Such materials have been widely concerned for their strong absorption of visible light. In this paper, the preparation methods of MOFs containing BODIPY chromophore were summarized. The structure characteristics, photophysical properties and application prospect of this kind of materials were discussed. Finally, the prospect and development trend of this kind of materials in the future are prospected. This paper can provide reference for the development of such materials in the field of photochemistry. |
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