刘军,周全,谢佳琦,赖申枝.化学通报,2020,83(1):17-22.
Pd基催化剂在分解甲酸析氢中的研究进展
Application of Pd-based Catalysts for Hydrogen Evolution from Formic Acid Decomposition
投稿时间:2019-06-01  修订日期:2019-10-08
DOI:
中文关键词:  氢能  甲酸分解  Pd基催化剂  催化选择性
英文关键词:Hydrogen energy  Formic acid decomposition  Palladium-based catalysts  Catalysis selectivity
基金项目:湖南省自然科学基金项目(2018JJ5021)资助
作者单位E-mail
刘军 湖南化工职业技术学院制药与生物工程学院 株洲 412000  
周全 湖南化工职业技术学院制药与生物工程学院 株洲 412000  
谢佳琦 湖南化工职业技术学院制药与生物工程学院 株洲 412000  
赖申枝 湖南化工职业技术学院制药与生物工程学院 株洲 412000 1395561744@qq.com 
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中文摘要:
      甲酸是最简单的羧酸,无色、低毒,在室温下便于运输和储存。最近,甲酸作为一种最有前景的储氢材料,在室温下采用异相催化剂分解甲酸制氢气引起了科研工作者的广泛关注。和其他催化剂相比,Pd基催化剂在温和条件下催化甲酸分解制备氢气方面表现出优良的性能,是一种非常理想的非均相催化剂。本文介绍了多种Pd基催化剂的性能特点、制备方法和其在催化甲酸分解制备氢气领域的研究进展,并对其未来研究发展方向进行展望。
英文摘要:
      Formic acid is the simplest carboxylic acid. It is colorless, low toxicity, and easy to transport and store at room temperature. Recently, formic acid is one of the most promising hydrogen storage materials, and the use of heterogeneous catalysts to decompose formic acid to produce hydrogen at room temperature has attracted wide attention of researchers. Compared to the other catalysts, Pd-based catalysts exhibit excellent performance for the decomposition of formic acid to yield hydrogen under mild condition. The properties and preparation methods of Pd-based catalysts and the applications in the fields of the production of hydrogen from formic acid decomposition are reviewed. The future research directions of Pd-based catalysts are also discussed.
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