王喆,赵志西.化学通报,2020,83(1):23-29.
砷迁移释放过程中吸附-脱附作用机制的研究进展
Research Advances of the Adsorption-Desorption Mechanism in Arsenic Mobilization and Retention
投稿时间:2019-08-14  修订日期:2019-11-06
DOI:
中文关键词:    吸附-脱附  静电吸附  离子交换  络合形态
英文关键词:Arsenic  Adsorption-desorption  Electrostatic attraction  Ion exchange  Complexation species
基金项目:国家自然科学基金项目(41867051)、新疆维吾尔自治区高校科研计划项目(XJEDU2017M022)和天山青年计划项目(2018Q025)资助
作者单位E-mail
王喆 新疆师范大学化学化工学院 乌鲁木齐 830054  
赵志西 新疆师范大学化学化工学院 乌鲁木齐 830054 zhixizhao@qq.com 
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中文摘要:
      高砷地下水污染是一个全球性的环境问题。在特定地质、地貌、气候和水文及水化学条件下,含砷矿物发生吸附-脱附反应,砷元素迁移和释放进入水体,导致高砷地下水生成并危害周围人群健康。本文在系统总结前人研究工作基础上,从吸附质和吸附剂两方面讨论了竞争吸附、氧化还原、pH和有机质等因素对砷吸附-脱附行为的影响,总结得到三种砷吸附-脱附控制机制,即静电吸附机制、离子交换机制和络合形态机制。本文可以为揭示高砷地下水发生机制以及开展砷污染控制和治理提供有益帮助。
英文摘要:
      High arsenic pollution in groundwater is a global environmental issue. Under specific geological, geomorphological, climatic and hydrological and hydrochemical conditions, arsenic-containing minerals undergo adsorption and desorption reactions. Therefore the arsenic was released into groundwater and caused the formation of high arsenic groundwater. Based on the previous researches, the mechanism of adsorption-desorption during arsenic migration and intention in groundwater was analyzed and summarized. Effects of competitive adsorption, redox, pH and organic matter on arsenic adsorption-desorption were discussed from the aspects of adsorbate and adsorbent. Three mechanisms on arsenic adsorption-desorption, i.e. electrostatic attraction mechanism, ion exchange mechanism and complexation species mechanism, were summarized. This paper can provide useful help for revealing the mechanism of high arsenic groundwater and conducting arsenic pollution control and treatment.
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