王明皓,陈明森,许国锋,吴思.化学通报,2020,83(7):600-609,587. |
偶氮苯高分子的光致可逆固液转变 |
Photoinduced Reversible Solid-to-liquid Transitions of Azopolymers |
投稿时间:2020-02-10 修订日期:2020-03-09 |
DOI: |
中文关键词: 偶氮苯 偶氮苯高分子 光致固液转变 |
英文关键词:Azobenzene Azopolymer Photoinduced solid-to-liquid transition |
基金项目:青年千人计划和安徽省自然科学基金项目(1908085MB38)资助 |
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中文摘要: |
偶氮苯化合物是一种极具吸引力以及较为常用的光响应材料,本文主要介绍偶氮苯的光响应性质以及一些偶氮苯高分子的合成方法,解析光化学反应导致偶氮苯高分子固液转变的机理,并介绍其在粘结性材料、光致动器、光致热导开关器件及非热纳米压印中的应用。 |
英文摘要: |
Azobenzene compounds are very attractive and commonly used photoresponsive materials. This minireview mainly introduced the photoresponsive property of azobenzene. The syntheses and the mechanisms of photoinduced reversible solid-to-liquid transitions of some azobenzene-containing polymers (azopolymers) were further introduced. The potential applications of azopolymers based on photoinduced reversible solid-to-liquid transitions were also presented, such as adhesive materials, photoactuators, photothermally conductive switching devices and non-thermal nanoimprinting. |
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