| 孔勇.化学通报,2020,83(9):792-798. |
| N-杂环卡宾配体在聚合反应中的研究进展 |
| Research Advances of N-Heterocyclic Carbene Ligands in Polymerization |
| 投稿时间：2020-03-02 修订日期：2020-05-07 |
| DOI： |
| 中文关键词: N-杂环卡宾 金属配合物催化剂 聚合反应 |
| 英文关键词:N-heterocyclic carbene Metal complex catalysts Polymerization |
| 基金项目:国家科技重大专项（2016ZX05021004-002）和中石化科技部项目（PE19001、P18001-2、P17002-8）资助 |
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| 中文摘要: |
| N-杂环卡宾（NHC）配体的优异催化性能引起了人们的广泛关注，已成功应用于多种烯烃聚合反应。本文主要介绍NHC及其在开环易位聚合、烯烃配位聚合和原子转移自由基聚合等反应中的应用。在此基础上，指出了今后NHC配体在聚合反应研究的发展方向。 |
| 英文摘要: |
| N-heterocyclic carbene ligands have attracted extensive attention due to their excellent catalytic performance, and have been widely utilized in a variety of olefin polymerization reactions. According to the recent reports, N-heterocyclic carbene were briefly introduced, firstly. The recent research advances of the application in ring-opening metathesis polymerization, olefin coordination polymerization, atom transfer radical polymerization, and other polymerization were focused on. The development trends of N-heterocyclic carbene ligands in polymerization were also prospected. |
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