| 许阳,廖礼豪,赵晓丹.化学通报,2020,83(11):970-976. |
| 硒π酸催化合成含氮杂环化合物的研究进展 |
| Progress in the Synthesis of Aza-Heterocyclic Compounds via Selenium-π-Acid Catalysis |
| 投稿时间：2020-05-19 修订日期：2020-07-05 |
| DOI： |
| 中文关键词: 含氮杂环化合物 硒π酸催化 合成方法 |
| 英文关键词:Aza-heterocyclic compounds Selenium-π-acid catalysis Synthetic methods |
| 基金项目:国家自然科学基金项目（21772239，91856109）资助 |
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| 中文摘要: |
| 含氮杂环化合物具有独特的生理和药理活性，它们的高效合成引起了广大科研工作者的研究兴趣。近年来，发展了不同的合成方法制备含氮杂环化合物。其中，硒π酸催化合成含氮杂环化合物的合成方法因反应条件温和、操作简单、区域选择性和官能团兼容性好的优点受到越来越多的关注。本文综述了近些年来硒π酸催化合成含氮杂环化合物如吲哚衍生物、四氢吡咯衍生物、二氢喹嗪衍生物、噁唑衍生物、吡唑并喹唑啉酮类衍生物、异喹啉类衍生物及2-咪唑烷酮衍生物等的研究进展。 |
| 英文摘要: |
| The unique physiological and pharmacological activity of aza-heterocyclic compounds has aroused the interest of researchers. In recent years, many synthetic methods for the synthesis of aza-heterocyclic compounds have been reported. Among them, selenium-π-acid catalysis has attracted extensive attention due to mild reaction conditions, simple operation, and good regioselectivity and functional group compatibility. This short review convers the progress in the synthesis of aza-heterocyclic compounds such as indoles, pyrrolidines, dihydroquinolizidines, oxazoles, pyrazolo quinazolinones, isoquinolines, and 2-imidazolidone derivatives by selenium-π-acid catalysis. |
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