陈辉,王清福,刘婷婷,张垚,周铎,李云飞.化学通报,2021,84(3):232-239. |
廉价金属铁、钴、锰配合物催化的加氢/脱氢反应研究进展 |
Progress in Hydrogenation/Dehydrogenation Reactions Catalyzed by Non-Noble Metal Complexes of Iron, Cobalt and Manganese |
投稿时间:2020-07-09 修订日期:2020-09-11 |
DOI: |
中文关键词: 铁 钴 锰 金属配合物 催化 |
英文关键词:Iron Cobalt Manganese Metal complexes Catalysis |
基金项目:河南省科学院科研开发项目(200403001,200503001,200603035,200603041,200603108)和河南省青年人才托举工程项目(2021HYTP005)资助 |
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中文摘要: |
催化加氢和脱氢反应是现代化学工业的发展核心。从毫克级有机化学反应探索到吨级化学品的生产,均存在催化加氢和脱氢反应的广泛应用。长期以来,贵金属催化剂是实现含氮及含氧化合物催化加氢和脱氢反应的关键所在。从绿色环保及可持续发展的角度出发,近年来廉价金属催化的加氢和脱氢反应取得了重要的研究进展,本文主要介绍在非贵金属催化的加氢和脱氢转化研究中取得的重要进展。 |
英文摘要: |
Catalytic hydrogenation and dehydrogenation reactions are the core of the modern chemical industry. From the exploration of milligram-level organic chemical reactions to the production of tons of chemicals, there are wide applications of catalytic hydrogenation and dehydrogenation reactions. For a long time, precious metal catalysts have been the key to the catalytic hydrogenation and dehydrogenation of nitrogen-containing and oxygen-containing compounds. From the perspective of environmental protection and sustainable development, in recent years, non-noble metal-catalyzed hydrogenation and dehydrogenation reactions have made important research progress. This review aims to introduce the significant progress made in the development of non-noble metal-catalyzed hydrogenation and dehydrogenation conversions. |
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