马红艳,李霞.化学通报,2021,84(4):322-329. |
离子液体功能化环糊精化合物的合成及应用 |
Syntheses and Applications of Ionic Liquid Functionalized Cyclodextrin Compound |
投稿时间:2020-09-10 修订日期:2020-12-29 |
DOI: |
中文关键词: 环糊精 离子液体 大环化合物 合成 应用 |
英文关键词:Cyclodextrin Ionic liquid Macrocyclic compound Synthesis Application |
基金项目:国家自然科学基金项目(21605133)资助 |
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中文摘要: |
离子液体功能化环糊精化合物(ILs-CD)兼具环糊精“内疏水、外亲水”的结构特性和离子液体的低毒性、低蒸气压、电化学窗口宽、热稳定性和化学稳定性高等特性,是一类有巨大发展潜力的新型大环化合物。本文主要根据合成的ILs-CD化合物的阳离子不同对其进行了分类,并介绍了其合成方法,同时阐述了其在电化学、环境、食品、医药、催化、分子印迹、分离分析等不同领域的应用;并对ILs-CD化合物的未来发展方向进行展望,为ILs-CD化合物的制备和应用提供参考依据。 |
英文摘要: |
The ionic liquid functionalized cyclodextrin compound (ILs-CD) combines the “internally hydrophobic and externally hydrophilic” cavities of cyclodextrin and the low toxicity, low vapor pressure, wide electrochemical window, thermal stability and high chemical stability from ILs. So ILs-CD is a new type of macrocyclic compound with great development potential. This article mainly classifies the synthesized ILs-CD compounds ascording to their different cations, and introduces their synthesis methods. Meanwhile, the applications of ILs-CD in different fields such as in electrochemistry, environment, food, medicine, catalysis, molecular imprinting technology and separation analysis were elaborated. The current situation and development of ILs-CD were summarized. This will provide the help for the preparation and application of ILs-CD in the future. |
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