| 杨圣雄,奚江波,肖 菲,马 鑫,田 心,池 凯,肖军武,王帅.化学通报,2021,84(7):643-653. |
| 限域化学：碳基功能材料从基础研究到应用 |
| Confined Chemistry: From Basic Research to Application of Carbon-Based Materials |
| 投稿时间：2021-01-06 修订日期：2021-02-06 |
| DOI： |
| 中文关键词: 限域化学 碳基功能材料 催化 储能 印刷技术 |
| 英文关键词:Confined chemistry, Carbon-based materials, Catalysis, Energy storage, Printing technology |
| 基金项目:国家自然科学基金项目(51772110,21874051)和湖北省自然科学基金项目(2019CFB539)资助 |
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| 中文摘要: |
| 限域化学是纳米尺度限域空间内的化学行为。限域空间内的化学环境不同于常规本体溶液,因而会出现许多奇特的现象,如反应选择性增强,活性增加,稳定性提高。本文结合本课题组近年来的工作,对限域化学领域碳基功能材料的限域策略简要介绍,包括限域界面诱导、限域化学组装印刷及三维多孔受限体系,并阐述了其在催化、储能方面的应用。最后提出了限域化学未来发展面临的主要挑战,期望能为此领域研究提供参考。 |
| 英文摘要: |
| Confined chemistry refers to the chemical behavior in a confined space at the nanometer scale. The difference of chemical environment between the confined space and conventional bulk solution generates many peculiar phenomena, such as enhanced reaction selectivity, increased activity, and improved stability. Based on the research work of our group in recent years, this paper briefly introduces confinement strategies of carbon-based functional materials in the confined chemistry field, including confined interface induction, confined chemical assembly and printing, and three-dimensional porous confined system.And applications in catalysis and energy storage are presented. Finally, the review provides an outlook on challenges in further development of the confined chemistry, which could be helpful for researchers in this field. |
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