| 邹莹兵,詹渟婷,马秀玲,刘键熙,陈前火.化学通报,2021,84(11):1130-1140. |
| 导电MOFs在能源转化中的应用 |
| Conductive MOFs for Energy Conversion |
| 投稿时间：2021-03-28 修订日期：2021-04-27 |
| DOI： |
| 中文关键词: 导电金属有机框架 电催化 水分解 氧还原反应 二氧化碳还原 |
| 英文关键词:conductive metal-organic frameworks, electrocatalysis, water splitting, oxygen reduction reaction, CO2 reduction |
| 基金项目:国家自然科学基金项目(21673039,21573042,21805039,21971038,21975044)和福建省自然科学基金项目(2020J01151)资助 |
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| 中文摘要: |
| 可再生能源供应方案包括析氢反应(HER)、析氧反应(OER)、氧还原反应(ORR)和二氧化碳还原反应(CO2RR)等多种反应，电催化剂对这些反应至关重要。到目前为止，已有一系列导电MOFs作为与能源相关电催化电极材料的报道。本文从提高MOFs导电能力和对产物的选择性、增强MOFs的化学稳定性及增加MOFs的反应活性位点等方面介绍了导电MOFs作为电催化剂的设计策略，重点综述了其在能源转化涉及的HER、OER、ORR以及CO2RR方面的应用，并从材料制备和应用需求角度出发, 对高性能导电MOFs材料在电催化领域所面临的挑战和前景进行了展望。 |
| 英文摘要: |
| Renewable energy provision schemes involve several reactions such as hydrogen evolution reaction (HER), oxygen evolution reaction (OER), oxygen reduction reaction (ORR) and carbon dioxide reduction reaction (CO2RR). and electrocatalysts are crucial for these systems. Up to now, several conductive MOFs have been reported as electrode materials for the energy-related electrocatalytic applications. In this paper, the design strategies of the conductive MOFs as electrocatalysts were introduced from the aspects of improving the conductivity, selectivity, stability and the reaction active sites. And the applications of conductive MOFs materials in HER, OER, ORR, and CO2RR related to energy conversion were mainly reviewed. From the perspective of material preparation and application requirements, the challenges and prospects of high-performance conductive MOFs materials as electrocatalysts are prospected. |
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