| 宋国强,霍利岭,李竞草.化学通报,2021,84(11):1186-1190. |
| 过渡金属催化C-H键活化的硅氢化反应 |
| Hydrosilylation of C-H bond activation catalyzed by transition metal |
| 投稿时间：2021-03-29 修订日期：2021-05-25 |
| DOI： |
| 中文关键词: 硅氢化反应 催化 过渡金属 |
| 英文关键词:Hydrosilylation reactionn, Catalysis, Transition metal |
| 基金项目: |
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| 中文摘要: |
| 过渡金属催化C-H键活化的硅氢化反应在材料科学和合成化学领域里具有重要意义。有机硅化合物在纺织、橡胶、机械、日化等材料领域有广泛应用,此外,它还是重要的有机合成中间体,作为亲核试剂应用到Hiyama偶联反应,反应具有经济、高效、环境友好等特点。近些年来,很多课题组在该领域进行研究,并取得了一定的成果[1]。我们将从过渡金属催化芳基/烷基C-H键活化的硅氢化反应出发,介绍近些年在此领域的研究进展。 |
| 英文摘要: |
| Transition metal catalyzed hydrogenation of C-H bond is of great significance in the fields of materials science and synthetic chemistry. Silicone compounds are widely used in textile, rubber, machinery, daily chemical and other materials. In addition, they are also important organic synthesis intermediates. As nucleophile, they are applied to Hiyama coupling reaction, and the reaction has the characteristics of economy, high efficiency and environment friendly. In recent years, many research groups have carried out researches in this field and achieved certain results. We will introduce the recent progress in this field, starting from the hydrogenation reaction of aryl/alkyl C-H bond activation catalyzed by transition metals. |
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