| 荆祺,孙京.化学通报,2022,85(2):203-210. |
| 可见光促进的偕二氟烯烃制备与应用研究进展 |
| Recent advances in the synthesis and applications of gem-difluoroalkenes promoted by visible light |
| 投稿时间：2021-05-29 修订日期：2021-07-12 |
| DOI： |
| 中文关键词: 可见光催化 偕二氟烯烃 C-F键活化 |
| 英文关键词:Visible light photocatalysis, gem-Difluoroalkenes, C-F bond activation |
| 基金项目:辽宁省教育厅基本科研项目(L2019037)资助 |
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| 中文摘要: |
| 偕二氟烯烃化合物在医药、材料、精细化工等领域具有广泛地应用，同时也是一类非常重要的有机合成中间体用于制备各类复杂的有机氟化合物。可见光催化反应具有条件温和，绿色清洁等特点，已经成为有机化学中非常重要的合成手段之一。本文综述了近年来可见光促进的偕二氟烯烃化合物的制备及其在有机合成化学中的应用。 |
| 英文摘要: |
| gem-Difluoroalkene derivatives have a wide range of application in medical chemistry, material chemistry and fine chemicals. In addition， they are versatile synthetic intermediates for the preparation of more complex fluorinated compounds. Visible-light-promoted organic reactions have become one of the most important synthetic methods in organic chemistry due to their mild, green and efficiency. This review summarizes the recent progress in the synthesis and applications of gem-difluoroalkenes promoted by visible light in organic synthesis. |
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