| 付凤艳,邢广恩,王晓红,高志华,牛丽丽.化学通报,2022,85(2):211-220. |
| 聚合物微观结构对聚合物电解质膜性能的影响 |
| Importance of Polymer Microstructure on Performance of Polymer Electrolyte Membranes |
| 投稿时间：2021-06-17 修订日期：2021-07-24 |
| DOI： |
| 中文关键词: 聚合物电解质膜 相分离 微观结构 离子传导率 |
| 英文关键词:Polymer electrolyte membranes Phase separation Microstructure Ion conductivity |
| 基金项目:河北省高等学校科学研究项目(BJ2019206)、衡水学院高层次人才科研启动基金项目(2018GC10)、衡水市科技计划项目(2020011006Z)、河北省重点研发计划项目(18214321)和国家级大学生创新创业训练计划项目(202010101001)资助 |
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| 中文摘要: |
| 聚合物的微观结构是设计具有优异的电化学性能的聚合物电解质膜的基础。在电解质膜中,相分离结构形成的离子簇和离子通道可以影响膜在高温低湿度条件下的离子传导和水的传输,这种结构形成的形貌也可以影响膜的吸水率、溶胀度、碱稳定性等性能。近几年来,人们对于具有微观相分离形貌的聚合物电解质膜的合成和形貌开展了很多研究。本文主要综述了无规共聚物,嵌段共聚物和接枝共聚物等聚合物电解质膜的结构和性能的关系。 |
| 英文摘要: |
| Polymer microstructure is important in order to design novel polymer electrolyte membranes (PEMs) with excellent electrochemical performance. The ionic clusters and channels formed by the phase separation structure play a critical role in PEMs, affecting ion conductivity and water transport, especially at medium temperature and low relative humidity (RH). In addition, physical properties such as water uptake, dimensional swelling and alkaline stability behavior depend strongly on polymer morphology. Over the past few decades, much research has focused on the synthetic development and microstructural characterization of PEM materials. In this paper, the relationship between structure and properties of PEMs such as random copolymers, block copolymers and graft copolymers are introduced in detail. |
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