| 曹福臣,贺天平.化学通报,2022,85(7):884-890. |
| 硼烯：从理论模型到探究应用 |
| Boronene: From Theoretical Model to Inquiry application |
| 投稿时间：2021-11-02 修订日期：2021-11-25 |
| DOI： |
| 中文关键词: 硼烯 理论模型 实验制备 应用前景 |
| 英文关键词:Boronene, Theoretical Model, Experimental Preparation, Application Prospects |
| 基金项目: |
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| 中文摘要: |
| 1993年,我国科学家唐敖庆通过理论计算提出了一种基于碳和硼的共轭多面体为硼烯的理论模型研究奠定了基础。随后在新的理论和计算方法不断提出下硼烯的理论模型得到了进一步的完善,2007年,美国耶鲁大学的唐慧等人通过理论计算提出了完全处于同一平面的硼烯理论模型,至此二维硼烯的概念得到了广泛地确信。2015年,美国的曼尼克斯和我国的吴克辉等人几乎同时分别在Ag(111)衬底上生成了硼烯薄膜。随后,科学家们通过实验探究发现硼烯在超导材料、电池电极材料、催化剂、储氢等领域有巨大的应用前景。硼烯的发展史揭示了理论和实验交互验证的新型科学发展模式,促进了二维材料发展观的演进。 |
| 英文摘要: |
| In 1993, Chinese scientist Aoqing Tang proposed a conjugated polyhedron based on carbon and boron through theoretical calculations, which laid the foundation for the theoretical model study of boronene. Subsequently, the theoretical model of boronene was further improved under the continuous proposals of new theories and calculation methods. In 2007, Tang Hui of Yale University in the United States and others put forward a theoretical model of boronene that is completely on the same plane through theoretical calculations. The concept of boronene has been widely believed. In 2015, Mannix of the United States and Wu Kehui of China respectively formed borene films on Ag(111) substrates at the same time. Subsequently, the scientists discovered through experimental exploration that boronene has huge application prospects in the fields of superconducting materials, battery electrode materials, catalysts, and hydrogen storage. The development history of boronene reveals a new scientific development model of interactive verification of theory and experiment, and promotes the evolution of the development concept of two-dimensional materials. |
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