| 赵学艳,肖瑞杰,曹桂荣.化学通报,2022,85(10):1209-1218. |
| 表面活性离子液体参与构筑的胶束体系 |
| Micelle Systems Based on Surface Active Ionic Liquids |
| 投稿时间：2022-02-24 修订日期：2022-03-31 |
| DOI： |
| 中文关键词: 表面活性离子液体 胶束 聚集行为 表面活性剂 |
| 英文关键词:Surface-active ionic liquids, Micelle, Aggregation behavior, Surfactant |
| 基金项目:廊坊市科技局科学技术研究与发展计划项目(2021011041)和中央高校基本科研业务费专题项目(ZY20215158)资助 |
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| 中文摘要: |
| 离子液体的可设计性,使得新型表面活性离子液体不断涌现,从而将具有不同功能基团的离子液体引入到了传统的有序分子聚集体中,这也将有助于实现有序分子聚集体的可控性和功能化。本文综合评述了表面活性离子液体在水溶液及离子液体中的胶束化行为,重点总结了烷基碳链长度、阴离子结构和阳离子结构对表面活性离子液体聚集行为的影响,介绍了新型功能性表面活性离子液体在水溶液中的胶束化行为,分析了表面活性离子液体与传统表面活性剂复配体系的协同增效作用,并探讨了表面活性离子液体构建的胶束体系的发展方向。 |
| 英文摘要: |
| Due to the designability of ionic liquids, new kinds of surface active ionic liquids (SAILs) continue to spring up. It is helpful to achieve the controllability and functionalization of ordered molecular aggregates by the introduction different functional groups into ionic liquids. In this paper, the micellization of SAILs in aqueous solution and ionic liquids is comprehensively reviewed. The effects of alkyl carbon chain length, anion structure and cation structure of SAILs on the aggregation behavior are discussed in detail. The micellar behavior of new functional SAILs in aqueous solution is summarized. The synergistic effect of the compound systems composed of SAILs and conventional surfactants is analyzed. Finally, the future development of micelle systems based on SAILs is prospected. |
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