| 李彦洗,龚奇菡,薄雅文,迟克彬,姜桂元.化学通报,2023,86(5):523-534. |
| 用于电解水制氢的过渡金属MOFs基催化剂 |
| Transition metal MOFs-based materials for hydrogen evolving reaction from water electrolysis |
| 投稿时间：2022-08-25 修订日期：2022-09-15 |
| DOI： |
| 中文关键词: 金属有机框架材料 催化剂 氢能 析氢反应 |
| 英文关键词:Metal organic frameworks, Catalyst, Hydrogen energy, Hydrogen evolving reaction |
| 基金项目:中国石油天然气股份有限公司直属院所基金项目(2020-CB-05-06)和中国石油天然气股份有限公司科学研究与技术开发项目(2021DG1901)资助 |
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| 中文摘要: |
| 金属有机框架材料(MOFs)因具有无机和有机的杂合性质、高度有序的多孔性、结构可修饰性、比表面积大和孔隙率高等特点，在催化领域具有广阔的应用前景。本文从氢能的开发利用角度出发，在纯MOFs、MOFs复合及衍生材料三个方面对近十年来过渡金属MOFs基催化剂在电解水制氢方面的重要研究进展进行了系统综述，着重针对材料的合成进行了探讨，以及在基础研究和产业应用的角度指出当前过渡金属MOFs基制氢催化剂面临的挑战和机遇，对其应用前景进行展望。 |
| 英文摘要: |
| Metal-organic frameworks (MOFs) have broad application prospects in the field of catalysis due to their hybrid inorganic and organic properties, highly-ordered porosity, structural modifiability, large specific surface area, and high porosity. From the perspective of the development and utilization of hydrogen energy, this paper systematically reviews the important progress of transition metal MOFs-based catalysts in water electrolysis for hydrogen production in the past ten years from three aspects: pure MOFs, MOFs composites and derived materials. The material synthesis is discussed, and the challenges and opportunities of the current transition metal MOFs-based catalysts for hydrogen production are pointed out from the perspectives of basic research and industrial applications, and their application prospects are prospected. |
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