| 卢博,陈芳圆,任淑慧,万屏南,李靖聪,欧阳雯婷,林艳,崔汉峰.化学通报,2023,86(4):491-494,504. |
| 二茂铁基三烯酮类姜黄素类似物的合成、晶体结构及电化学性质 |
| Synthesis, crystal structure and electrochemical properties of ferrocene-based trienone curcumin analogues |
| 投稿时间：2022-09-14 修订日期：2022-10-21 |
| DOI： |
| 中文关键词: 二茂铁 三烯酮 合成 晶体结构 电化学性质 |
| 英文关键词:Ferrocene Trienone Synthesis Crystal structure Electrochemical property |
| 基金项目:国家自然科学基金项目(82160729)、江西省教育厅科学技术研究项目(GJJ201226,GJJ190668,GJJ211234)和江西省中医药管理局科技计划项目(2022A379)资助 |
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| 中文摘要: |
| 以不同取代基的肉桂醛和二茂铁为起始原料,经Vilsmeier-Haack甲酰化反应、Claisen-Schmidt反应三步合成5种新型二茂铁基三烯酮类衍生物,其结构经1H NMR,、13C NMR和HRMS(ESI-TOF)表征,并用X-ray单晶衍射确定了5d的晶体结构,其构型为反式构型,电化学研究表明化合物5a具有较高氧化还原活性。 |
| 英文摘要: |
| Five new ferrocene-based trienone curcumin analogues were synthesized in three steps by Vilsmeier-Haack formylation and Claisen-Schmidt reactions using ferrocene as starting material. Their structures were characterized by 1H NMR, 13C NMR and HRMS (ESI-TOF), and the crystal structure of 5d was determined by X-ray single-crystal diffraction, and the conformation was trans. Electrochemical studies showed that compound 5a has high redox activity. |
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