| 滑淑清,孙京,周明东.化学通报,2023,86(7):775-783,823. |
| 非均相离子液体催化CO2环加成反应研究进展 |
| Progress of heterogeneous ionic liquid catalyzing CO2 cycloaddition reaction |
| 投稿时间：2022-11-30 修订日期：2022-12-29 |
| DOI： |
| 中文关键词: 负载型离子液体 CO2 碳酸酯 催化 环氧化物 |
| 英文关键词:Supported ionic liquid CO2 Carbonate Catalysis Epoxide |
| 基金项目:辽宁省教育厅基本科研项目(L2019037)资助 |
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| 中文摘要: |
| 二氧化碳（CO2）是一种来源丰富的C1资源，在温和条件下实现CO2的资源化利用是当前研究的热点之一。CO2环加成反应制备环状碳酸酯是CO2资源化利用的重要途径之一。环状碳酸酯是电池电解液的优良介质，可承受较恶劣的光、热及化学变化；同时也是聚氨酯、聚碳酸酯等精细化工中间体，广泛应用于医药、化工、纺织、印染等领域。非均相离子液体催化剂具有化学和热稳定性好、合成过程简单和可重复使用等优势。本文重点总结了近年来非均相离子液体催化剂在CO2和环氧化物环加成反应中的应用，并对非均相离子液体催化CO2环加成反应的发展进行展望。 |
| 英文摘要: |
| Carbon dioxide (CO2) is a rich source of C1 resources, and the utilization of CO2 under mild conditions is one of the current research hotspots. Producing cyclic carbonate is one of the important pathways for CO2 utilization. Cyclic carbonate is an excellent medium for battery electrolyte, which can withstand harsh light, heat and chemical changes. At the same time, it is also a fine chemical intermediate such as polyurethane and polycarbonate, which is widely used in pharmaceutical, chemical, textile, printing and dyeing fields. Ionic liquid heterogeneous catalysts have the advantages of good chemical and thermal stability, simple synthesis process and reusability. In this paper, the applications of ionic liquid heterogeneous catalysts in the reaction of CO2 with epoxides are summarized, and the development of heterogeneous ionic liquid catalyzed cycloaddition reaction of CO2 is prospected. |
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