| 姜雅坤,李飞岳,张汀慧,冯晓春,冯上体,王程宇.化学通报,2023,86(8):985-994,984. |
| 可见光诱导下磺酰氯参与的C-磺酰基化合物的合成研究进展 |
| Progress in synthesis of C-sulfonyl compounds involvingsulfonyl chloride under visible light |
| 投稿时间：2022-12-21 修订日期：2023-01-30 |
| DOI： |
| 中文关键词: 可见光 磺酰氯 自由基反应 磺酰化 |
| 英文关键词:Visible light Sulfonyl chloride Radical reaction Sulfonylation |
| 基金项目:临沂大学大学生创新创业训练计划项目(X202210452192)和山东省自然科学基金面上项目(ZR2022MB130)资助 |
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| 中文摘要: |
| C-磺酰基化合物在医药、材料、合成化学等领域具有广泛的应用,其合成方法一直是有机化学工作者们的研究热点。可见光催化具有成本低、易获得和环境友好等特点,其诱导的磺酰基自由基反应已成为合成砜类化合物的重要手段。磺酰氯廉价、易获得、种类多,是一类重要的磺酰基自由基前体。本文介绍了近年来在可见光催化下,磺酰氯参与的C-磺酰基化合物的合成研究进展。按照可见光催化剂种类：Ir配合物、Ru配合物、无外加光敏剂以及其他类型光催化剂等,进行分类归纳讨论,并对相应的反应机理进行了阐述,为今后此类反应在有机合成中的应用提供参考,并指出该领域研究面临的挑战及发展方向。 |
| 英文摘要: |
| Sulfonyl compounds have been widely used in medicine, materials, synthetic chemistry. Visible light catalysis is characterized by low cost, easy availability and environmental friendliness. Its induced sulfonyl radical reaction has become an important means to synthesize sulfones. Sulfonyl chloride is a kind of important precursor of sulfonyl radical because of its cheapness, availability and variety. In this paper, the synthesis methods of C-sulfonyl compounds involving sulfonyl chloride under visible light are reviewed, including: Ir complex, Ru complex, no external photosensitizer and other types of photocatalysts, according to the types of visible light catalysts. Their mechanisms, challenges, development directions were also discussed, which may provide a reference for the application of such reactions in organic synthesis in the future. |
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