| 栗艳丽,袁振东[],侯燕.化学通报,2024,87(2):190-202,189. |
| 从碳中心到硅中心:手性螺环双膦配体研究的发展 |
| From the carbon center to the silicon center: Advances of Chiral Spiro Diphosphine Ligands |
| 投稿时间：2023-05-05 修订日期：2023-06-25 |
| DOI： |
| 中文关键词: 手性螺环双膦配体 螺环骨架 双膦配体 不对称催化 |
| 英文关键词:Chiral spiral bisphosphine ligand, Spiral skeleton, Bisphosphine ligand, Asymmetric catalysis |
| 基金项目: |
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| 中文摘要: |
| 手性螺环配体和催化剂已被公认是一类优势手性配体和催化剂。手性螺环配体的相关研究，促进了不对称催化领域的发展。根据螺环骨架类型进行分类，分别讨论具有螺[4.4]壬烷骨架、螺二氢茚骨架、螺[4.4]壬二烯骨架以及螺二色烷骨架的手性螺环双膦配体的合成及在不对称催化反应中的应用，为今后发展新的不对称催化体系提供了重要参考。 |
| 英文摘要: |
| Chiral spiral ligands and catalysts have been recognized as a class of dominant chiral ligands and catalysts. The research on chiral spiral ligands has promoted the development of asymmetric catalysis. The synthesis and application of chiral spiral bisphosphine ligand with spiral [4.4] nonane skeleton, spiral dihydroindene skeleton, spiral [4.4] nonadiene skeleton and Spirodichroic skeleton in asymmetric catalytic reactions were discussed, which provided an important reference for developing new asymmetric catalytic systems in the future. |
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