| 王丽苹,阮玉娴,李仁星,余莹,陈琳,姜帅.化学通报,2023,86(12):1409-1425. |
| Fe-MILs系可见光响应复合材料在光诱导反应中的应用研究进展 |
| ProgressinApplicationofFe-MILs-DerivedCompositeswithVisibleLightResponseinLight-InducedReactions |
| 投稿时间：2023-05-22 修订日期：2023-07-14 |
| DOI： |
| 中文关键词: 金属骨架有机材料，来瓦希尔骨架材料，可见光，光催化 |
| 英文关键词:Metal-organic frameworks, materials of institut Lavoisier, visible light, photocatalysis |
| 基金项目:云南省地方本科高校基础研究联合专项(202001BA070001-175)、云南省本科高校转型发展课题(2015BZGB11)、云南省高校绿色催 化与能源材料科技创新团队项目、云南省大学生创新创业训练计划项目(S202210684021、S202210684023、S202310684009)、曲靖师范学 院重点课程项目(ZDKC2016005)、云南省高校协同创新中心(曲靖绿色光伏产业协同创新中心)项目、云南省科技厅科技人才与平台计 划项目(202305AF150088)、云南省李和兴专家工作站项目和曲靖市科创企业孵化中心有限公司横向项目资助 |
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| 中文摘要: |
| 能源危机和环境问题已成为人类社会面临和亟待解决的两个重大问题。光催化技术被认为是解决能源危机和环境问题有效方法之一。来瓦希尔骨架材料（MILs）是一类著名的金属骨架有机材料（MOFs）。Fe-MILs是MILs系列材料中一个重要的分支，其带隙宽度约为2.39 eV ~ 2.79 eV，能被可见光激发。然而，Fe-MILs存在光的利用率低、导电性差、光生电子-空穴复合快、光腐蚀等缺点。近年来，研究者们采用多种方法对Fe-MILs进行改性，制备了很多Fe-MILs衍生的可见光响应复合材料，并将这些材料成功用于光诱导反应。本文主要综述了近年来Fe-MILs衍生的可见光响应复合材料在水的分解、CO2还原、有机物转化、光催化固氮等多个领域的应用研究，并对Fe-MILs光催化剂的发展提出了建议。 |
| 英文摘要: |
| The energy crisis and environmental problem have become two major problems facing and urgently solved by human society. Photocatalytic technology is regarded as one of the effective ways to solve energy crisis and environmental problem. Materials of institut Lavoisier (MILs) is a famous class of metal-organic frameworks (MOFs). Fe-MILs is an important branch of the MILs series of materials with band gaps of about 2.39 eV ~ 2.79 eV and can be excited by visible light. However, Fe-MILs have disadvantages such as low light utilization, poor conductivity, fast photoelectron-hole composite and light corrosion. In recent years, the researchers have modified Fe-MILs with various methods, prepared many Fe-MILs-derived composites with a visible light response and successfully used them for light-induced reactions. In this work, the application of Fe-MILs-derived composites with the visible light response in water splitting, CO2 reduction, organic matter transformation, photocatalytic nitrogen fixation, Cr(VI) reduction, gaseous Hg0 removal, degradation of dyes and pharmaceutical and personal care products are reviewed, and the development trend of Fe-MILs-derived photocatalyst is proposed. |
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